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ESTCP 2017 Project-of-the-year Award for Environmental Restoration
1,4-Dioxane, a cyclic diether used as an additive in chlorinated solvents is a common and persistent groundwater contaminant. While conventional soil vapor extraction (SVE) can remove some 1,4-dioxane, a substantial residual source is left behind causing long-term groundwater contamination. Due to the compound’s complete miscibility in water, 1,4-dioxane becomes sequestered in the vadose zone pore water which serves as a long-term source of groundwater contamination.
Dr. Rob Hinchee from Integrated Science & Technology, Inc. and his team led a project that aimed to evaluate and demonstrate the efficacy of enhanced or extreme soil vapor extraction (XSVE) designed specifically to remove 1,4-dioxane from the vadose zone by incorporating enhancements such as increased air flow, increased temperature and focused vapor extraction. A screening-level mass and energy balance model, HypeVent XSVE, was developed to simulate the remediation of 1,4-dioxane by XSVE.
The study results indicate that 1,4-dioxane concentrations in the treatment zone decreased about 95% and soil moisture decreased about 45%. Downward migration of 1,4-dioxane due to condensation was not observed. HypeVent XSVE adequately simulated 1,4-dioxane removal, soil moisture and soil temperatures observed during the demonstration. Sensitivity analyses showed that 1,4-dioxane removal benefited considerably from heated air injection.
XSVE has been demonstrated to be a cost-effective remediation approach 1,4-dioxane in the vadose zone, which may reduce the need for long-term groundwater remediation. HypeVent XSVE has been demonstrated to be a useful feasibility assessment and design tool for XSVE of 1,4-dioxane.
For this significant work, Dr. Hinchee and his team received the 2017 ESTCP Project of the Year Award for Environmental Restoration for their project titled 1,4-Dioxane Remediation by Extreme Soil Vapor Extraction (XSVE).
Project Team
Dave Burris, IST, accepts the 2017 ESTCP Project of the Year Award for Environmental Restoration on behalf of lead principal investigator, Rob Hinchee. Back Row (left to right): Yuanming Guo, Arizona State; Paul Johnson, Colorado School of Mines; Paul Dahlen, Arizona State. Front Row: Andrea Leeson, ESTCP; Dave Burris, IST; Herb Nelson, ESTCP. (Photo by Trish Gottesman)